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Steel: An iron base alloy, malleable under
proper conditions, containing up to 2% carbon
(seldom exceeds 1.7%). Alloys with high proportion of other elements
and a relatively small amount of iron, are still
called steel if the iron and carbon are
important influencing elements.
Iron is a major component and primary
element in steel. Carbon is
the major alloying element. 90% of the steels
produced through out the world is referred to as
carbon steel. Iron
weighs 7.86 g/cm3 or 490 /lb/ft3df.
melting point of iron is 1535°
C (2795° F) and
boils at 3000° C
(5432° F). It is
fourth most abundant element by weight in the
crust of the earth and makes up most of the core
of the earth. Pure iron is soft, malleable, and
ductile and has very useful property of being
magnetic. Small amounts of some elements such as
manganese, sulphur, silicon, chromium,
molybdenum, phosphorus are also added to steel
to improve its properties
Iron ores from which iron is extracted are
Magnetite, Hematite and Taconite.
Magnetite is combination of ferric oxide and
ferrous oxide (Fe2O3 &
FeO). It is a black ore containing about
15% iron. Magnetite is strongly magnetic.
Hematite is red blood in color and is
basically ferric oxide or rust (Fe2O3).
It is a low grade ore than magnetite and has 50%
iron. Taconite is a green low grade core which had
30% iron. Other ores are limonite, siderite, marcesite
and iron pyrites.
Limonite ( FeO.H2O)is a hydrated
ferrous oxide. Siderite is ferrous carbonate
(FeCO3) and iron pyrites and
marcesite are iron sulphides (FeS). These ores
are of poor quality in iron content, often less
than 10%.
Carbon exists in small quantity in ferrite
and in cementite. Iron and carbon together form
a compound called iron carbide (Fe3C)
in which one carbon atom is bonded to three iron
atoms. When steel is raised to a red heat and
cooled suddenly, it is hardened by the formation
of the hard carbide Fe3C. The
eutectic point, or the saturation point of the
dissolving of the carbon in the iron is 0.83%
above which point the excess carbon is thrown
out as free graphite unless other elements are
present to take it up.
Some of steels according to manufacturing
process
Dirty steel is steel with inclusion of iron
oxide from scrap used in the converter or of
aluminum oxide from the aluminum used in
deoxidizing. The melting point of steel varies
with carbon, but is always higher than that of
cast iron with the same amount of combined
carbon.
Open hearth steel is made by fusing cast iron
with steel scrap or wrought iron in a
regenerative furnace. Cementation consists of
heating bars of wrought iron in contact with
carbon. This is called blister steel as surface
is covered with Blisters. Blister steel has a
crystalline fracture decreasing toward the
center of the bar where there is less carbon.
Shear steel is produced from this blister
steel by cutting and piling together, heating to
a high temperature and rolling or hammering into
bars.
Bessemer steel is made by carburizing cast
iron by forcing a powerful blast of air through
molten iron.
Crucible steel is made by melting wrought
iron in a crucible with charcoal and
ferromanganese or special steel mixes in a
crucible furnace. The slag separates by gravity
from the molten steel in the crucibles and the
oxides combine with carbon and manganese or
aluminum and boil off. The crucible process
permits a high degree of control and reduces
sulphur and phosphorus.
Electric steel is made in either the
induction of arc type furnace and is of uniform
quality and of a higher strength and ductility
than open-hearth steel of the same carbon
content.
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